Surface Passivation of CIGS Solar Cells Using Gallium Oxide

Garud, Siddharta;Gampa, Nikhil;Allen, Thomas G.;Kotipalli, Ratan;Vermang, Bart;et.al.
(2018) Physica Status Solidi. A: Applications and Materials Science (Print) — Vol. 215, n° 1700826, p. 6 (2018)

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Authors
  • Garud, SiddhartaHelmholz Zentrum Berlin/Germany
    Author
  • Gampa, NikhilIMEC Leuven/Belgium
    Author
  • Allen, Thomas G.Australian National University, Canberra/Australia
    Author
  • Kotipalli, RatanUCLouvain
    Author
  • Author
  • Vermang, BartHasselt University, Belgium
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Abstract
This work proposes gallium oxide grown by plasma‐enhanced atomic layer deposition, as a surface passivation material at the CdS buffer interface of Cu (In, Ga) Se2 (CIGS) solar cells. In preliminary experiments, a metal‐insulator‐semiconductor (MIS) structure is used to compare aluminium oxide, gallium oxide, and hafnium oxide as passivation layers at the CIGS‐CdS interface. The findings suggest that gallium oxide on CIGS may show a density of positive charges and qualitatively, the least interface trap density. Subsequent solar cell results with an estimated 0.5 nm passivation layer show an substantial absolute improvement of 56 mV in open‐circuit voltage (VOC), 1 mA cm− 2 in short‐circuit current density (JSC), and 2.6% in overall efficiency as compared to a reference (with the reference showing 8.5% under AM 1.5 G).
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Citations

Garud, S., Gampa, N., Allen, T. G., Kotipalli, R., Flandre, D., Batuk, M., Hadermann, J., Meuris, M., Poortmans, J., Smets, A., & Vermang, B. (2018). Surface Passivation of CIGS Solar Cells Using Gallium Oxide. Physica Status Solidi. A: Applications and Materials Science (Print), 215(1700826), 6. https://doi.org/10.1002/pssa.201700826 (Original work published 2018)