Structural insight into the magnesium borohydride – ethylenediamine solid-state Mg-ion electrolyte system
(2023) Dalton Transactions — Vol. 52, p. 2404-2411 (2023)
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- A highly complex crystal structure of stoichiometric Mg5(en)6(BH4)10 was solved from single crystal synchrotron X-ray diffraction and confirmed by neutron powder diffraction (NPD) on isotopically substituted Mg(en)1.2(11BD4)2. We highlight the role of the amorphous Mg(BH4)2 in the reactivity of the Mg(BH4)2-en system and characterized a previously overlooked phase, Mg(en)2(BH4)2.
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Golub, I., Heere, M., Gounaris, V., Li, X., Steenhaut, T., Wang, J., Robeyns, K., Li, H., Dovgaliuk, I., Ikeda, K., Hautier, G., & Filinchuk, Y. (2023). Structural insight into the magnesium borohydride – ethylenediamine solid-state Mg-ion electrolyte system. Dalton Transactions, 52, 2404-2411. https://doi.org/10.1039/D2DT03567G (Original work published 2023)