Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(iii) complexes
(2018) Physical Chemistry Chemical Physics — Vol. 20, n° 43, p. 27256-27260 (2018)
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- Authors
Bevernaegie, Robin 
Marcélis, Lionel Moreno-Betancourt, Angélica Laramée-Milette, Baptiste
- Abstract
- Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(III) complexes. We showed that its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calculations and spectroelectrochemistry.
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Citations
Bevernaegie, R., Marcélis, L., Moreno-Betancourt, A., Laramée-Milette, B., Hanan, G. S., Loiseau, F., Sliwa, M., & Elias, B. (2018). Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(iii) complexes. Physical Chemistry Chemical Physics, 20(43), 27256-27260. https://doi.org/10.1039/c8cp04265a (Original work published 2018)