TIME-RESOLVED SAXS STUDIES OF MORPHOLOGICAL-CHANGES IN COLD CRYSTALLIZED POLY(ETHYLENE-TEREPHTHALATE) DURING ANNEALING AND HEATING

Jonas, Alain;RUSSELL, TP;YOON, DY
(1994) Colloid and Polymer Science : : Kolloid-Zeitschrift und Zeitschrift für Polymere — Vol. 272, n° 11, p. 1344-1351 (1994)

Files

No attached file found for this publication.

Details

Authors
Abstract
Structural changes occurring during crystallization of quenched amorphous poly(ethylene terephthalate) (PET) and subsequent cooling/heating cycles have been studied by real-time small-angle x-ray scattering (SAXS), using synchrotron radiation. Initial crystallization is found to occur by insertion of new lamellae between the existing ones, while rapid continuous melting/recrystallization happens when the cold-crystallized PET samples are heated above the previous highest annealing temperature. Such melting/recrystallization results in irreversible increases in the lamellar long period, the crystal thickness and the density difference between the crystalline and amorphous regions; in contrast, at temperatures below the prior highest crystallization temperature, the structural changes are dominated by reversible effects such as thermal expansion. However, throughout the entire temperature range up to the melting point around 250 degrees C, the crystal core thickness remains quite small, less than ca. 50 Angstrom, and the linear crystallinity of lamellar stacks remains nearly constant around 0.3. Such a low crystallinity indicates the presence of thick order-disorder interfacial layers on the lamellar surface, whose thickness increases with temperature.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Jonas, A., RUSSELL, T., & YOON, D. (1994). TIME-RESOLVED SAXS STUDIES OF MORPHOLOGICAL-CHANGES IN COLD CRYSTALLIZED POLY(ETHYLENE-TEREPHTHALATE) DURING ANNEALING AND HEATING. Colloid and Polymer Science : : Kolloid-Zeitschrift und Zeitschrift für Polymere, 272(11), 1344-1351. https://hdl.handle.net/2078.5/270516 (Original work published 1994)