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Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines

Hu, Lei;Chakraborty, Sayandip;Tumanov, Nikolay;Wouters, Johan;Berionni, Guillaume;et.al.
(2024) Chemical Communications — Vol. 60, p. 7073-7076 (2024)

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Authors
  • Hu, LeiUCLouvain
    Author
  • Chakraborty, SayandipUNamur
    Author
  • Tumanov, Nikolayorcid-logoUNamur
    Author
  • Wouters, JohanUNamur
    Author
  • Robiette, Raphaëlorcid-logoUCLouvain
    Author
  • Berionni, Guillaumeorcid-logoUNamur
    Author
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Abstract
Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.
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Hu, L., Chakraborty, S., Tumanov, N., Wouters, J., Robiette, R., & Berionni, G. (2024). Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines. Chemical Communications, 60, 7073-7076. https://doi.org/10.1039/d4cc01868k (Original work published 2024)