Confinement effects of a crystalline sponge on ferrocene and ferrocene carboxaldehyde

Brunet , Gabriel;Safin, Damir;Robeyns, Koen;Facey, Glenn A.;Murugesu, Muralee;et.al.
(2017) Chemical Communications — Vol. 53, p. 5645-5648 (2017)

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Authors
  • Brunet , GabrielUniversity of Ottawa (Canada)
    Author
  • Safin, DamirUCLouvain
    Author
  • Robeyns, KoenUCLouvain
    Author
  • Facey, Glenn A.University of Ottawa (Canada)
    Author
  • Filinchuk, YaroslavUCLouvain
    Author
  • Murugesu, MuraleeUniversity of Ottawa (Canada)
    Author
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Abstract
The pivotal role of p p interactions in the inclusion behaviour of a series of organometallic sandwich compounds is studied through single-crystal X-ray diffraction. The confinement effects of a crystalline sponge host are investigated where, notably, we observe an enhanced rotation of the ligand ring once encapsulated by the nanoporous framework, as evidenced by SSNMR experiments.
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Brunet, G., Safin, D., Robeyns, K., Facey, G. A., Korobkov, I., Filinchuk, Y., & Murugesu, M. (2017). Confinement effects of a crystalline sponge on ferrocene and ferrocene carboxaldehyde. Chemical Communications, 53, 5645-5648. https://doi.org/10.1039/c7cc02470c (Original work published 2017)