One-pot aerosol route to MoO3-SiO2-Al2O3 catalysts with ordered super microporosity and high olefin metathesis activity

Debecker, Damien;Stoyanova, Mariana;Colbeau-Justin , Fréderic;Rodemerck, Uwe;Sanchez, Clément;et.al.
(2012) Angewandte Chemie (International Edition) — Vol. 51, n° 9, p. 2129-2131 (2012)

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Authors
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  • Stoyanova, MarianaUniversität Rostock
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  • Colbeau-Justin , FrédericUniversité de Paris 06
    Author
  • Rodemerck, UweUniversität Rostock
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  • Sanchez, ClémentUniversité de Paris 06
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Abstract
Aerosol processing coupled with surfactant-templated sol–gel synthesis is used to produce MoO3-SiO2-Al2O3 catalysts. By quenching the sol–gel kinetics by fast drying of the aerosol, molecular-scale dispersion of each component is achieved. The structuring agent generates an organized porosity at the nanoscale. The catalysts have a high specific surface area and outstanding olefin metathesis activity.
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Citations

Debecker, D., Stoyanova, M., Colbeau-Justin, F., Rodemerck, U., Boissière, C., Gaigneaux, E., & Sanchez, C. (2012). One-pot aerosol route to MoO3-SiO2-Al2O3 catalysts with ordered super microporosity and high olefin metathesis activity. Angewandte Chemie (International Edition), 51(9), 2129-2131. https://doi.org/10.1002/anie.201106277 (Original work published 2012)