Structure and Low-temperature Thermal-conductivity of Pyrolytic Boron-nitride

Duclaux, Laurent;Nysten, Bernard;Issi, Jean-Paul;Moore, A. W.

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  • Duclaux, LaurentUCLouvain
    Author
  • Author
  • Issi, Jean-PaulUCLouvain
    Author
  • Moore, A. W.
    Author
Abstract
The microstructure and morphology of three samples of pyrolytic boron nitride deposited at different temperatures have been characterized with use of x-ray diffraction and thermal-conductivity measurements. The x-ray analysis allowed the determination of the mean interlayer spacing, the out-of-plane coherence length, and the crystallites preferred orientation. It revealed the presence of three distinct morphologies. The thermal conductivity was measured as a function of temperature in the range 1. 5 < T < 300 K. The temperature variations of the thermal conductivity were fitted by using a model previously developed for the analysis of the thermal conductivity of graphites and carbons. This fit allowed the determination of the in-plane coherence length. It also allowed the analysis of point-defect concentration and of the interlayer shear modulus. It is shown that low-temperature thermal-conductivity measurements may be used to complement x-ray diffraction data for the microstructural characterization of materials.
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