The specific heat of fullerenes extract (C60/C70) has been measured in the temperature range 4 < T < 560 K. The temperature variation of the specific heat exhibits an anomalous behaviour. Below 80 K, it presents a classical temperature variation with a dependence close to a T3 below 10 K. The measurements bring two transitions to the fore : one around 250 K corresponding to the well known orientational phase transition, and the other around 90 K which is attributed to the freezing of the rotational motion of the molecules.
Grivei, E., Nysten, B., Cassart, M., Demain, A., & Issi, J.-P. (1993). Specific-heat of Fullerenes Extract. Solid State Communications, 85(2), 73-75. https://doi.org/10.1016/0038-1098(93)90349-R (Original work published 1993)