Sulfur resistance and high activity of hydrated manganese sulfate in the catalytic oxidation of methanethiol

Cellier, C.;Gaigneaux, Eric;Grange, Paul
(2004) Journal of Catalysis — Vol. 222, n° 1, p. 255-259 (2004)

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Abstract
Hydration of manganese sulfate at a low reaction temperature (150 degreesC) induces high heterogeneous catalytic activity and stability in the oxidation of methanethiol. The temperature of the reaction controls the reversible change of structure, i.e., hydration/dehydration processes as well as the associated changes of activity and selectivity. (C) 2003 Elsevier Inc. All rights reserved.
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Cellier, C., Gaigneaux, E., & Grange, P. (2004). Sulfur resistance and high activity of hydrated manganese sulfate in the catalytic oxidation of methanethiol. Journal of Catalysis, 222(1), 255-259. https://doi.org/10.1016/j.jcat.2003.10.029 (Original work published 2004)