Diastereoselective synthesis of vinylcyclopropanes from dienes and sulfur ylides

Robiette, Raphaël;Marchand-Brynaert, Jacqueline
(2008) Synlett : accounts and rapid communications in synthetic organic chemistry — n° 4, p. 517-520 (2008)

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The reaction of aryl- and vinyl-stabilized sulfonium ylides with electron-poor dienes has been investigated. Clear] cyclopropanation to 2-aryl- and 2-vinyl-substituted vinylcyclopropanes, with high regio- and stereocontrol, was observed. This new diastereoselective strategy was applied to formal synthesis of lamoxirene and dictyopterene B.
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Robiette, R., & Marchand-Brynaert, J. (2008). Diastereoselective synthesis of vinylcyclopropanes from dienes and sulfur ylides. Synlett : accounts and rapid communications in synthetic organic chemistry, 4, 517-520. https://doi.org/10.1055/s-2008-1032080 (Original work published 2008)