Selected polyazole based coordination polymers displaying functional properties
(2020) Advances in Inorganic Chemistry — Vol. 76, n° 1, p. 121-153 (2020)
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- In this account, we present recent on-going developments on the design and synthesis of transition metal (M(II) = Fe, Cu, Zn, Cd, Hg) coordination networks built from 1,2,4-triazole, tetrazole, benzimidazole or pyrazole building blocks. Special focus is placed on the use of a high energetic material made of a dissymmetric 1,2,4-triazole-tetrazole ligand, able to provide coordination polymers of alkali metals and alkaline earth metals, as well as salts. These materials, apart from their structural diversity and appeal, present some potential applications in gas or metallic storage, molecular electronics (spin crossover), gas sensing, toxic metal sensing and capture, as well as in medicinal applications.
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Garcia, Y. (2020). Selected polyazole based coordination polymers displaying functional properties. Advances in Inorganic Chemistry, 76(1), 121-153. https://doi.org/10.1016/bs.adioch.2020.04.001 (Original work published 2020)