CDW in FeCl4−—Graphite Intercalation Compounds Studied by STM

Daulan, Christine;Roux, Jean-Claude;Flandrois, Serge;Saadaoui, Hassan;Nysten, Bernard
(1994) Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals — Vol. 244, n° 1, p. 379-384 (1994)

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  • Daulan, ChristineCRPP, Bordeaux, France
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  • Roux, Jean-ClaudeCRPP, Bordeaux, France
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  • Flandrois, SergeCRPP, Bordeaux, France
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  • Saadaoui, HassanCRPP, Bordeaux, France
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  • Nysten, Bernardorcid-logoUCLouvain
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Abstract
Samples of graphite electrochemically intercalated with FeCl4 − in CH3NO2 solution are studied by scanning tunneling microscopy (STM) from a submicrometer to atomic scale. A new long range triangular modulation of the charge density is observed on the surface. This modulation is superimposed on the usual graphite periodicity. This new structure is tentatively attributed to a charge density wave (CDW) resulting from the charge transfer between the intercalated species and the graphite host.
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Daulan, C., Roux, J.-C., Flandrois, S., Saadaoui, H., & Nysten, B. (1994). CDW in FeCl4−—Graphite Intercalation Compounds Studied by STM. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 244(1), 379-384. https://doi.org/10.1080/10587259408050133 (Original work published 1994)