The (4+1) Annulation Reaction between 1,3-Diene and Sulfonium Ylide

Rousseau, Olivier
(2014) Ph.D. Student’s Day — Location: Louvain-la-Neuve (23.May.2014)

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  • Rousseau, OlivierUCLouvain
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Abstract
In order to access easily to five-membered carbocycles, a new methodology was developed. It involves a sulfonium ylide (instead of carbene, commonly used for this reaction) and a electron poor 1,3-diene. Sulfonium ylides are indeed known to be more easily generated and handled than carbenes. This methodology was applied to various 1,3-dienes and ylides. An asymmetric version of this reaction was also successfully carried out, using chiral sulfonium ylides, leading to excellent enantiomeric excesses.
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Rousseau, O. (2014). The (4+1) Annulation Reaction between 1,3-Diene and Sulfonium Ylide. Ph.D. Student’s Day, Louvain-la-Neuve. https://hdl.handle.net/2078.5/49932