Radiation-chemistry of N-hexane Aqueous-solutions As Studies By Chromatographic Analysis of Final Products
(1991) Societes Chimiques Belges. Bulletin — Vol. 100, n° 2, p. 107-113 (1991)
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- Radiolysis of dilute oxygen-free hexane aqueous solutions give dodecanes isomers analyzed by capillary gas chromatography. The relative yields for radicals which react by radical-radical recombination reactions are 39 %, 32 % and 29 % for primary hexyl radical, secondary-2 hexyl radical and secondary-3 hexyl radical respectively. This distribution is changed with the N2O saturation before the radiolysis to 22 %, 42 % and 37 %. If the first distribution is statistic, the increase of OH available to attack the solute gives the distribution existing in pure alkane radiolysis.
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Dedoncker, J., & Tilquin, B. (1991). Radiation-chemistry of N-hexane Aqueous-solutions As Studies By Chromatographic Analysis of Final Products. Societes Chimiques Belges. Bulletin, 100(2), 107-113. https://doi.org/10.1002/bscb.19911000202 (Original work published 1991)