Efficient and stereoselective synthesis of allylic ethers and alcohols

Pospisil, Jiri;Marko, Istvan
(2006) Organic Letters — Vol. 8, n° 26, p. 5983-5986 (2006)

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Authors
  • Pospisil, JiriUCLouvain
    Author
  • Marko, IstvanUCLouvain
    Author
Abstract
A short and efficient synthesis of allylic TBS ethers and allylic alcohols has been developed, based upon a unique Kocienski - Julia olefination reaction. Allylic alcohols and allylic ethers are obtained in good to excellent yields and with high ( E)- selectivity. The conditions are mild and the procedure is broadly applicable.
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Citations

Pospisil, J., & Marko, I. (2006). Efficient and stereoselective synthesis of allylic ethers and alcohols. Organic Letters, 8(26), 5983-5986. https://doi.org/10.1021/ol062433y (Original work published 2006)