Competitive preferential solvation theory of weak molecular interactions
(1978) Journal of the Chemical Society. Faraday Transactions I — Vol. 74, p. 2210-2228 (1978)
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- Abstract
- The use of linear Bensi-Hildebrand, Scott or Scatchard equations to characterize molecular interactions leads frequently to anomalous results which cannot be interpreted easily in terms of traditional concepts. The situation is more serious for weak interactions, whose study requires the use of high concentrations of interacting partners. A simple theory is proposed (competitive preferential solvation theory or COPS theory) which can reasonably account for the observed anomalies without employing ad hoc arguments for individual problems. The theory is applied to a series of eighteen molecular interactions involving some degree of charge-transfer.
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Nagy, O. B., Muanda, M. Wa., & Nagy, J. B. (1978). Competitive preferential solvation theory of weak molecular interactions. Journal of the Chemical Society. Faraday Transactions I, 74, 2210-2228. https://hdl.handle.net/2078.5/85832 (Original work published 1978)