Catalytic, enantioselective, inverse electron-demand Diels-Alder reactions of 2-pyrone derivatives

Marko, Istvan;Evans, GR.;Seres, P.;Chelle, I;Janousek, Z.
(1996) 8th IUPAC Symposium on Organometallic Chemistry Dircted Towards Organic Synthesis (OMCOS) — Location: SANTA BARBARA(Ca) (6.August.1995)

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  • Marko, IstvanUCLouvain
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  • Evans, GR.
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  • Seres, P.
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  • Chelle, I
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  • Janousek, Z.
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Abstract
The lanthanide-catalysed, diastereo- and enantio-controlled Inverse Electron-Demand Diels-Alder cycloadditions of 3-carbomethoxy-2-pyrone derivatives with electron-rich dienophiles is shown to proceed with high levels of asymmetric induction.
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Marko, I., Evans, GR., Seres, P., Chelle, I., & Janousek, Z. (1996). Catalytic, enantioselective, inverse electron-demand Diels-Alder reactions of 2-pyrone derivatives. Pure and Applied Chemistry, 68(1), 113-122. https://doi.org/10.1351/pac199668010113 (Original work published 1996)