Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S) NP(S)(OiPr)2-1,5-S,S′}2]·CH 2Cl2

Babashkina, M.G.;Safin, Damir;Srebro, M.;Kubisiak, P.;Garcia, Yann;et.al.
(2012) CrystEngComm — Vol. 14, n° 2, p. 370-373 (2012)

Files

CrystEngComm_142012370-373.pdf
  • Restricted Access
  • Adobe PDF
  • 533.24 KB
Request a copy

Details

Authors
  • Babashkina, M.G.UCLouvain
    Author
  • Safin, DamirUCLouvain
    Author
  • Srebro, M.Jagiellonian University, Cracow (Poland)
    Author
  • Kubisiak, P.Jagiellonian University, Cracow (Poland)
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
Show more
Abstract
The reaction of the deprotonated N-thiophosphorylated thiourea 6-MeO(O)CC6H4NHC(S)NHP(S)(OiPr)2 (HL) with NiCl2 leads to violet [NiL2]·CH2Cl 2 crystals, which were isolated by recrystallization from a mixture of CH2Cl2 and n-hexane. It was established that the deprotonated ligands, L, are 1,5-S,S′-coordinated. The influence of CH2Cl2 for the complex stabilization was studied.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Babashkina, M. G., Safin, D., Srebro, M., Kubisiak, P., Mitoraj, M. P., Bolte, M., & Garcia, Y. (2012). Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S) NP(S)(OiPr)2-1,5-S,S′}2]·CH 2Cl2. CrystEngComm, 14(2), 370-373. https://doi.org/10.1039/c1ce06322g (Original work published 2012)