Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones.

De Dobbeleer, Corinne;Pospisil, Jiri;De Vleeschouwer, Freija;De Proft, Frank;Marko, Istvan
(2009) Chemical Communications — n° 16, p. 2142-2144 (2009)

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Authors
  • De Dobbeleer, Corinne
    Author
  • Pospisil, JiriUCLouvain
    Author
  • De Vleeschouwer, Freija
    Author
  • De Proft, Frank
    Author
  • Marko, IstvanUCLouvain
    Author
Abstract
The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent have been developed.
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De Dobbeleer, C., Pospisil, J., De Vleeschouwer, F., De Proft, F., & Marko, I. (2009). Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones. Chemical Communications, 16, 2142-2144. https://doi.org/10.1039/b901943j (Original work published 2009)