Complexation properties of the crown ether-containing N-thiophosphorylated thiourea towards Ni II

Babashkina, M.G.;Safin, Damir;Robeyns, Koen;Garcia, Yann
(2012) Dalton Transactions — Vol. 41, n° 5, p. 1451-1453 (2012)

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Abstract
Reaction of the deprotonated N-thiophosphorylated thiourea (4′-benzo-15-crown-5)NHC(S)NHP(S)(OiPr) 2 (HL) with NiCl 2 in aqueous EtOH leads to dark green [Ni(L-1,5-S,S′) 2]·2H 2O crystals that were isolated by recrystallization from a mixture of CH 2Cl 2 and n-hexane. © 2012 The Royal Society of Chemistry.
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Babashkina, M. G., Safin, D., Robeyns, K., & Garcia, Y. (2012). Complexation properties of the crown ether-containing N-thiophosphorylated thiourea towards Ni II. Dalton Transactions, 41(5), 1451-1453. https://doi.org/10.1039/c1dt11958c (Original work published 2012)