User-Friendly Platinum Catalysts for the Highly Stereoselective Hydrosilylation of Alkynes and Alkenes

Dierick, Steve;Vercruysse, Emilie;Berthon-Gelloz, Guillaume;Marko, Istvan
(2015) Chemistry: A European Journal — Vol. 21, n° 47, p. 17073-17078 (2015)

Files

2015_Dierick_Chemistry.pdf
  • Restricted Access
  • Adobe PDF
  • 475.21 KB
Request a copy

Details

Authors
  • Dierick, SteveUCLouvain
    Author
  • Vercruysse, EmilieUCLouvain
    Author
  • Berthon-Gelloz, GuillaumeUCLouvain
    Author
  • Marko, IstvanUCLouvain
    Author
Abstract
With a view to addressing the shortcomings of traditional catalysts, a new generation of outstanding N- heterocyclic carbene platinum(0) complexes for the hydrosilylation of unsaturated carbon-carbon bonds is reported. Their discovery and application to the stereoselective addition of various silanes to silylated alkynes, terminal acetylenes, and olefins is presented. Insights into the catalytic cycle and the origin of the stereoselectivity are also discussed
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Dierick, S., Vercruysse, E., Berthon-Gelloz, G., & Marko, I. (2015). User-Friendly Platinum Catalysts for the Highly Stereoselective Hydrosilylation of Alkynes and Alkenes. Chemistry: A European Journal, 21(47), 17073-17078. https://doi.org/10.1002/chem.201502643 (Original work published 2015)