Fourier-transform Spectroscopy of Carbonyl Sulfide From 1800 To 3120 Cm(-1) - the Normal Species

Belafhal, A.;Fayt, André;Guelachvili, G.
(1995) Journal of Molecular Spectroscopy — Vol. 174, n° 1, p. 1-19 (1995)

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Authors
  • Belafhal, A.
    Author
  • Fayt, AndréUCLouvain
    Author
  • Guelachvili, G.
    Author
Abstract
We have measured the FT spectrum of OCS from 1800 to 3120 cm(-1) with a resolution of 0.007 cm(-1). The spectra have been recalibrated to yield absolute uncertainties of 3 X 10(-5) cm(-1) throughout the whole range. For the normal isotopic species a total of 117 different vibrational transitions have been identified and analyzed, both for the frequencies and for the intensities. A new global rovibrational analysis of (OCS)-O-16-C-12-S-32 has been performed. Important effective Herman-Wallis terms are explained on the basis of eigenvectors. (C) 1995 Academic Press Inc.
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Belafhal, A., Fayt, A., & Guelachvili, G. (1995). Fourier-transform Spectroscopy of Carbonyl Sulfide From 1800 To 3120 Cm(-1) - the Normal Species. Journal of Molecular Spectroscopy, 174(1), 1-19. https://doi.org/10.1006/jmsp.1995.1264 (Original work published 1995)