XAS structural and electronic investigation of a new type of catalyst: AlGaPON

Delsarte, Stéphanie;Serin, V;Flank, AM;Villain, F;Grange, Paul
(1999) 10th International Conference on XAFS (XAFS X) — Location: ILLINOIS INST TECHNOL, CHICAGO (Il) (10.August.1998)

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  • Delsarte, StéphanieUCLouvain
    Author
  • Serin, V
    Author
  • Flank, AM
    Author
  • Villain, F
    Author
  • Grange, PaulUCLouvain
    Author
Abstract
Substitution of oxygen by nitrogen in galloaluminophosphate oxides leads to compounds, with properties and applications improved as compared to the oxide. The structural and electronic changes induced by the anionic substitution of oxygen by nitrogen on those amorphous compounds have been studied by XAS. The investigation of the EXAFS and XANES data have allowed us to highlight some structural changes; in particular the existence of mixed tetrahedra XOxNy (x being P, Al or Ga) have been demonstrated. Such a study is helpful in understanding the variations in the surface acido-basic properties of these compounds.
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Delsarte, S., Serin, V., Flank, A., Villain, F., & Grange, P. (1999). XAS structural and electronic investigation of a new type of catalyst: AlGaPON. Journal of Synchrotron Radiation, 6, 433-435. https://doi.org/10.1107/S0909049598015842 (Original work published 1999)