Crystal-structure and Solid-state Conformation of 5-hydroxy-8,9-dioxo-8,9-seco-5-alpha-cholestan-3-beta-yl Acetate
(1993) Societes Chimiques Belges. Bulletin — Vol. 102, n° 8, p. 539-544 (1993)
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- Abstract
- The molecular structure of the title compound, which might be a possible intermediate in the synthesis of 5,10:8,9-diseco-steroids (=steroklastanes), was determined by X-ray analysis. Hydrogen bonding between the 5alpha-hydroxyl group and the 9-oxo function attached to the ten-membered ring, and the presence of two conformational forms of the side-chain in the solid state structure of 2 are established.
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Tinant, B., Declercq, J.-P., Dabovic, M., Krstic, N., Lorenc, L., & Mihailovic, ML. (1993). Crystal-structure and Solid-state Conformation of 5-hydroxy-8,9-dioxo-8,9-seco-5-alpha-cholestan-3-beta-yl Acetate. Societes Chimiques Belges. Bulletin, 102(8), 539-544. https://doi.org/10.1002/bscb.19931020806 (Original work published 1993)