Highly active and selective platinum(0)-carbene complexes. Efficient, catalytic hydrosilylation of functionalised olefins
(2004) Advanced Synthesis & Catalysis — Vol. 346, n° 12, p. 1429-1434 (2004)
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- Abstract
- Readily available N-heterocyclic platinum-carbene complexes 1 are highly efficient catalysts for the regioselective hydrosilylation of alkenes. These novel organometallics tolerate a wide range of functional and protecting groups, can be stored for prolonged periods of time and are particularly active (TON > 10(6)).
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Marko, I., Declercq, J.-P., Sterin, S., Buisine, O., Berthon, G., Michaud, G., & Tinant, B. (2004). Highly active and selective platinum(0)-carbene complexes. Efficient, catalytic hydrosilylation of functionalised olefins. Advanced Synthesis & Catalysis, 346(12), 1429-1434. https://doi.org/10.1002/adsc.200404048 (Original work published 2004)