Copper-catalyzed addition of nucleophilic silicon to aldehydes

Cirriez, Virginie;Rasson, Corentin;Hermant, Thomas;Petrignet , J.;Riant, Olivier;et.al.
(2013) Angewandte Chemie (International Edition) — Vol. 52, n° 6, p. 1785-1788 (2013)

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Authors
  • Cirriez, VirginieUCLouvain
    Author
  • Rasson, CorentinUCLouvain
    Author
  • Hermant, ThomasUCLouvain
    Author
  • Petrignet , J.UCLouvain
    Author
  • Díaz Álvarez , J.UCLouvain
    Author
  • Robeyns, KoenUCLouvain
    Author
  • Riant, OlivierUCLouvain
    Author
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Abstract
How to train your silane: A new family of chiral copper(I) complexes that bear a bifluoride counteranion were prepared and used in the first example of the enantioselective transfer of a silyl group to an aldehyde. This procedure provides fast access to non-racemic α-hydroxysilanes in high enantioselectivities. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Cirriez, V., Rasson, C., Hermant, T., Petrignet, J., Díaz Álvarez, J., Robeyns, K., & Riant, O. (2013). Copper-catalyzed addition of nucleophilic silicon to aldehydes. Angewandte Chemie (International Edition), 52(6), 1785-1788. https://doi.org/10.1002/anie.201209020 (Original work published 2013)