Reactivity of (-)-cytisine and derivatives towards palladium salts. X-ray characterization of a new palladium complex of (-)-cytisine

Bouquillon, Sandrine;Rouden, Jacques;Muzart, Jacques;Lasne, Marie-Claire;Tinant, Bernard;et.al.
(2006) Comptes rendus. Chimie — Vol. 9, n° 10, p. 1301-1308 (2006)

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Authors
  • Bouquillon, Sandrine
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  • Rouden, Jacques
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  • Muzart, Jacques
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  • Lasne, Marie-Claire
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  • Tinant, BernardUCLouvain
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Abstract
Reactivity of (-)-cytisine and substituted cytisines towards PdCl2(MeCN)(2) and Pd(OAC)(2) has been studied. Two complexes of Pd(II), PdCl2((-)-cytisine)(2) and Pd(OAC)(2)((-)-cytisine)(2) were prepared. X-ray analysis of Pd(OAc)(2)((-)-cytisine)(2) revealed a square planar environment of the metal center and a trans geometry. Cytisine and N-methylcytisine have been combinated to Pd(OAc)(2) or PdCl2(MeCN)(2) to catalyze the oxidative kinetic resolution of phenethyl alcohol. (C) 2006 Academie des sciences. Published by Elsevier SAS. All rights reserved.
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Bouquillon, S., Rouden, J., Muzart, J., Lasne, M.-C., Hervieu, M., Leclaire, A., & Tinant, B. (2006). Reactivity of (-)-cytisine and derivatives towards palladium salts. X-ray characterization of a new palladium complex of (-)-cytisine. Comptes rendus. Chimie, 9(10), 1301-1308. https://doi.org/10.1016/j.crci.2006.05.002 (Original work published 2006)