A Flexible Route toward Polypropylene Model Compounds of Various Tacticities

Drooghaag, Xavier; Henry, Gaëtan; Marchand-Brynaert, Jacqueline

doi:10.1055/s-0030-1258233

A Flexible Route toward Polypropylene Model Compounds of Various Tacticities

Drooghaag, Xavier

;

Henry, Gaëtan

;

Marchand-Brynaert, Jacqueline

(2010) Synthesis : journal of synthetic organic chemistry — n° 21, p. 3755-3760 (2010)

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Authors

Drooghaag, XavierUCLouvain
Author
Henry, GaëtanUCLouvain
Author
Marchand-Brynaert, JacquelineUCLouvain
Author

Abstract

This paper reports the flexible synthesis of 2,4,6,8,10-pentamethylundecane (PMU) as well as a chromatographic method for the separation of its diastereoisomers. This strategy offers a unique opportunity to accede to three model compounds of polypropylene (PP) of different tacticities (i.e., isotactic, syndiotactic, and atactic PP).

Affiliations

UCLouvainSST/IMCN/MOST - Molecular Chemistry, Materials and Catalysis

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Drooghaag, X., Henry, G., & Marchand-Brynaert, J. (2010). A Flexible Route toward Polypropylene Model Compounds of Various Tacticities. Synthesis : journal of synthetic organic chemistry, 21, 3755-3760. https://doi.org/10.1055/s-0030-1258233 (Original work published 2010)