Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes

Moins, Sébastien;Martins, José;Krumpmann, Arnaud;Lemaur, Vincent;Coulembier, Olivier;et.al.
(2017) Chemical Communications — Vol. 53, p. 6899 (2017)

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Authors
  • Moins, SébastienUMons
    Author
  • Martins, JoséGhent University (Belgium)
    Author
  • Krumpmann, ArnaudUMons
    Author
  • Lemaur, VincentUMons
    Author
  • Gohy, Jean-FrançoisUCLouvain
    Author
  • Coulembier, OlivierUMons
    Author
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Abstract
The association of kinetic studies, DFT calculations and 1H–7Li NMR analyses allowed the control of the cyclo-ATRP of PEG9DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. Their potential to act as a solid-state polymer electrolyte in Li-ion batteries has been highlighted and may come from the supramolecular organization of the cyclo-PEG forming a Li+ diffusion channel.
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Moins, S., Martins, J., Krumpmann, A., Lemaur, V., Cornil, J., Delbosc, N., Decroly, A., Dubois, P., Lazzaroni, R., Gohy, J.-F., & Coulembier, O. (2017). Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes. Chemical Communications, 53, 6899. https://doi.org/10.1039/c7cc02385e (Original work published 2017)