Synthesis of Trifluoromethyl-allenes by gold-catalyzed rearrangement of propargyl benzyl ethers

Boreux, Arnaud;Lonca, Geoffroy H.;Riant, Olivier;Gagosz, Fabien
(2016) Organic Letters — Vol. 18, p. 5162-5165 (2016)

Files

org-lett-2016-arnaud1.pdf
  • Restricted Access
  • Adobe PDF
  • 1004.04 KB
Request a copy

Details

Authors
  • Boreux, ArnaudUCLouvain
    Author
  • Lonca, Geoffroy H.Ecole Polytechnique (Palaiseau - France)
    Author
  • Riant, OlivierUCLouvain
    Author
  • Gagosz, FabienEcole Polytechnique (Palaiseau - France)
    Author
Abstract
A new method for the synthesis of trifluoromethyl-allenes from easily accessible α-trifluoromethyl-propargyl benzyl ether derivatives following a gold-catalyzed intramolecular hydride transfer has been developed. Various di- and trisubstituted trifluoromethyl-allenes were obtained in good to excellent yields.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Boreux, A., Lonca, G. H., Riant, O., & Gagosz, F. (2016). Synthesis of Trifluoromethyl-allenes by gold-catalyzed rearrangement of propargyl benzyl ethers. Organic Letters, 18, 5162-5165. https://doi.org/10.1021/acs.orglett.6b02636 (Original work published 2016)