Ligand assisted cleavage of uranium oxo-clusters

Nocton, G.;Pécaut, J.;Filinchuk, Yaroslav;Mazzanti, M.
(2010) Chemical Communications — Vol. 46, n° 16, p. 2757-2759 (2010)

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Abstract
Dibenzoylmethanate replaces the bridging triflate ligands in uranium triflate polyoxo-clusters and cleaves the U12O20 core yielding the new [U6O4(OH)4(η-dbm) 12] dibenzoylmethanate (dbm-) cluster which slowly dissociates into a monomeric complex. This reactivity demonstrates the importance of bridging ligands in stabilizing uranium polyoxo-clusters. © 2010 The Royal Society of Chemistry.
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  • ESRF, Grenoble (France)Chimie

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Nocton, G., Pécaut, J., Filinchuk, Y., & Mazzanti, M. (2010). Ligand assisted cleavage of uranium oxo-clusters. Chemical Communications, 46(16), 2757-2759. https://doi.org/10.1039/b926580e (Original work published 2010)