keV fullerene interaction with hydrocarbon targets: Projectile penetration, damage creation and removal

Delcorte, Arnaud;Garrison, Barbara J.
(2007) Nuclear Instruments & Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms — Vol. 255, n° 1, p. 223-228 (2007)

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  • Delcorte, ArnaudUCLouvain
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  • Garrison, Barbara J.The Pennsylvania State University
    Author
Abstract
The physics of energetic fullerene projectile penetration, damage creation and sputtering in organic solids is investigated via molecular dynamics simulations. Two models are used, the first one based on a full atomistic description of the target and the second one, using a coarse-grain prescription that was recently developed and tested for a benzene molecular crystal [E. Smiley, Z. Postawa, I.A. Wojciechowski, N. Winograd, B. J. Garrison, Appl. Surf. Sci. 252 (2006) 6436]. The results explore the mechanism of energy transfer from the C-60 projectile to the organic target atoms/molecules through the comparison with significantly different projectiles (Argon) and samples (Ag crystal). The effects of the projectile energy on the penetration and fast energy transfer processes (200 fs) are also delineated. The second part of the results investigates the 'long term' consequences (20-50 ps) of fullerene impacts in hydrocarbon sample surfaces. In an icosane (C20H42) solid, a 5 keV C-60 projectile induces a crater of similar to 10 nm diameter surrounded by a similar to 4 rim wide rim and ejects similar to 70 intact molecules. More than 75% of the fragments generated by the fullerene in the surface are also sputtered away by the end of the event. The perspective considers the capabilities of fullerene projectiles for depth profile analysis of molecular samples by particle-induced desorption mass spectrometry. (c) 2006 Elsevier B.V. All rights reserved.
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Delcorte, A., & Garrison, B. J. (2007). keV fullerene interaction with hydrocarbon targets: Projectile penetration, damage creation and removal. Nuclear Instruments & Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 255(1), 223-228. https://doi.org/10.1016/j.nimb.2006.11.070 (Original work published 2007)