Diastereoselective, Lanthanide-catalyzed, Inverse Electron-demand Diels-alder (iedda) Reactions of 3-carbomethoxy-2-pyrone (3-cmp) Derivatives

Marko, Istvan;Evans, GR.
(1994) Tetrahedron Letters — Vol. 35, n° 17, p. 2767-2770 (1994)

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Authors
  • Marko, IstvanUCLouvain
    Author
  • Evans, GR.
    Author
Abstract
Cycloaddition reactions between the chiral 2-pyrone derivatives 3 and various dienophiles, catalysed by lanthanide shift reagents, afford bicyclic lactones 8 in high diastereomeric excesses.
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Marko, I., & Evans, GR. (1994). Diastereoselective, Lanthanide-catalyzed, Inverse Electron-demand Diels-alder (iedda) Reactions of 3-carbomethoxy-2-pyrone (3-cmp) Derivatives. Tetrahedron Letters, 35(17), 2767-2770. https://doi.org/10.1016/S0040-4039(00)77028-6 (Original work published 1994)