Influence of Axial Coordination On the G-factor Anisotropy of the Tetraimine Macrocyclic Cobalt(ii) Complex [co(c10h20n8)cl(h2o)]cl-center-dot-h2o

Ceulemans, A.;Debuyst, René;Dejehet, Fernand;Janssen, P.;Vanquickenborne, LG.
(1994) Inorganic Chemistry — Vol. 33, n° 14, p. 3188-3190 (1994)

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Authors
  • Ceulemans, A.
    Author
  • Debuyst, RenéUCLouvain
    Author
  • Dejehet, FernandUCLouvain
    Author
  • Janssen, P.
    Author
  • Vanquickenborne, LG.
    Author
Abstract
The single-crystal EPR and powder laser EPR spectra of the tetraimine Co(II) complex [Co(C10H20N8)-Cl(H2O)]Cl.H2O have been measured. It is shown that the axial coordination partially quenches the anisotropy of the phase-coupling ligand field term.

Citations

Ceulemans, A., Debuyst, R., Dejehet, F., Janssen, P., & Vanquickenborne, LG. (1994). Influence of Axial Coordination On the G-factor Anisotropy of the Tetraimine Macrocyclic Cobalt(ii) Complex [co(c10h20n8)cl(h2o)]cl-center-dot-h2o. Inorganic Chemistry, 33(14), 3188-3190. https://doi.org/10.1021/ic00092a029 (Original work published 1994)