Optical and electron paramagnetic resonance investigations of colour instabilities in amber glass as a function of melting temperature and batch redox conditions

Mestdagh, M.M.;Dauby, C.;Van Cangh, L.;Dupont, C.
(1983) Glass Technology — Vol. 24, n° 4, p. 184-191 (1983)

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  • Mestdagh, M.M.
    Author
  • Dauby, C.
    Author
  • Van Cangh, L.
    Author
  • Dupont, C.
    Author
Abstract
Soda-lime glasses containing different concentrations of iron, sulphate, and coke were melted with various thermal programmes. Optical and low temperature EPR measurements were made. The FeO/Fe/sub 2/O /sub 3/ and S/sup 2-//S/sup 6+/ ratios were correlated with the optical transmittance at 550 nm and the intensities of a set of EPR lines centred at g/sub eff/ sime 6. These new EPR lines are observed in iron-sulphur amber glass when the log sulphide to sulphate ratio exceeds -0.6: this value coincides with better fining conditions.
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Mestdagh, M. M., Dauby, C., Van Cangh, L., & Dupont, C. (1983). Optical and electron paramagnetic resonance investigations of colour instabilities in amber glass as a function of melting temperature and batch redox conditions. Glass Technology, 24(4), 184-191. https://hdl.handle.net/2078.5/43081 (Original work published 1983)