3-thio-claisen Rearrangement of the Allyl Vinyl Sulfonium Ion

Harvey, JN.;Viehe, HG.
(1995) Chemical Society. Journal. Chemical Communications — n° 22, p. 2345-2346 (1995)

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  • Harvey, JN.
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  • Viehe, HG.
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Abstract
Generated in situ, the parent allyl vinyl sulfonium ion rapidly undergoes the title rearrangement to give a gamma,delta-unsaturated thionium ion; a similar process appears to be involved in the reaction of phenyl vinyl sulfoxide with isobutene.
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Harvey, JN., & Viehe, HG. (1995). 3-thio-claisen Rearrangement of the Allyl Vinyl Sulfonium Ion. Chemical Society. Journal. Chemical Communications, 22, 2345-2346. https://doi.org/10.1039/c39950002345 (Original work published 1995)