Solvent-free, low-temperature, selective hydrogenation of polyenes using a bimetallic nanoparticle Ru-Sn catalyst

Hermans, Sophie;Raja, R.;Thomas, J.M.;Johnson, B.F.G.;Gleeson, D.;et.al.
(2001) Angewandte Chemie (International Edition) — Vol. 40, n° 7, p. 1211-1215 (2001)

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  • Hermans, SophieUCLouvain
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  • Raja, R.autre
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  • Thomas, J.M.autre
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  • Johnson, B.F.G.autre
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  • Gleeson, D.autre
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Abstract
The point of attachment of bimetallic Ru6Sn particles which are anchored to the pore walls of a highly dispersed high-area mesoporous silica is found to be the tin atom, as indicated by in situ and ex situ measurements. This catalyst displays high activity for the low-temperature, selective hydrogenation of cyclic polyenes under solvent-free conditions (see scheme).
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Hermans, S., Raja, R., Thomas, J. M., Johnson, B. F. G., Sankar, G., & Gleeson, D. (2001). Solvent-free, low-temperature, selective hydrogenation of polyenes using a bimetallic nanoparticle Ru-Sn catalyst. Angewandte Chemie (International Edition), 40(7), 1211-1215. https://doi.org/10.1002/1521-3773(20010401)40:7<1211::AID-ANIE1211>3.0.CO;2-P (Original work published 2001)