A (2r,5s)-2-o-anisyl-3-oxa-1-aza-2-phosphabicyclo[3.3.0]octane Borane Complex
(1994) Acta Crystallographica. Section C: Crystal Structure Communications — Vol. 50, p. 954-955 (1994)
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- Abstract
- (2R,5S)-2-(2-Methoxyphenyl)-3-oxa-1-aza-2-phos-phabicyclo[3.3.0]octane(P-B)borane, C12H19BNO2P, is one of a series of new chiral oxazaphospholidine-borane complexes used as catalysts in the enantioselective borane reduction of ketones. The structure and the absolute configuration about the P atom were determined.
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Brunel, JM., Declercq, J.-P., Buono, G., Baldy, A., & Feneaudupont, J. (1994). A (2r,5s)-2-o-anisyl-3-oxa-1-aza-2-phosphabicyclo[3.3.0]octane Borane Complex. Acta Crystallographica. Section C: Crystal Structure Communications, 50, 954-955. https://doi.org/10.1107/S0108270193011606 (Original work published 1994)