The thermal spin transition which occurs in the polymeric chain compound [Fe(NH(2)trz)(3)](NO3)(2) above room temperature has been investigated by zero-field muon spin relaxation (mu SR) (similar to 8-402 K). The depolarization curves are best described by a Lorentzian and a Gaussian line that represent fast and slow components respectively. The spin transition is associated with a hysteresis loop of width Delta T = 34 K (T-1/2(up arrow) = 346 K and T-1/2(down arrow) = 312 K) that has been delineated by the temperature variation of the initial asymmetry parameter. Comparison of zero-field and transverse field (20 Oe) mu SR measurements shows that diamagnetic muon species occur over the entire temperature range, a large fraction of muons being however paramagnetic. (c) 2005 Elsevier B.V. All rights reserved.
Ksenofontov, V., Garcia, Y., Campbell, S., Boland, Y., Lord, J., & Gutlich, P. (2006). Hysteresis in the spin transition regime of [Fe(NH(2)trz)(3)](NO3)(2) as probed by ZF-mu SR. Physica B: Condensed Matter, 374, 126-129. https://doi.org/10.1016/j.physb.2005.11.032 (Original work published 2006)