Hysteresis in the spin transition regime of [Fe(NH(2)trz)(3)](NO3)(2) as probed by ZF-mu SR

Ksenofontov, V;Garcia, Yann;Campbell, SJ;Boland, Yves;Gutlich, P;et.al.
(2006) Physica B: Condensed Matter — Vol. 374, p. 126-129 (2006)

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Authors
  • Ksenofontov, V
    Author
  • Garcia, Yannorcid-logoUCLouvain
    Author
  • Campbell, SJ
    Author
  • Boland, YvesUCLouvain
    Author
  • Gutlich, P
    Author
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Abstract
The thermal spin transition which occurs in the polymeric chain compound [Fe(NH(2)trz)(3)](NO3)(2) above room temperature has been investigated by zero-field muon spin relaxation (mu SR) (similar to 8-402 K). The depolarization curves are best described by a Lorentzian and a Gaussian line that represent fast and slow components respectively. The spin transition is associated with a hysteresis loop of width Delta T = 34 K (T-1/2(up arrow) = 346 K and T-1/2(down arrow) = 312 K) that has been delineated by the temperature variation of the initial asymmetry parameter. Comparison of zero-field and transverse field (20 Oe) mu SR measurements shows that diamagnetic muon species occur over the entire temperature range, a large fraction of muons being however paramagnetic. (c) 2005 Elsevier B.V. All rights reserved.
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Ksenofontov, V., Garcia, Y., Campbell, S., Boland, Y., Lord, J., & Gutlich, P. (2006). Hysteresis in the spin transition regime of [Fe(NH(2)trz)(3)](NO3)(2) as probed by ZF-mu SR. Physica B: Condensed Matter, 374, 126-129. https://doi.org/10.1016/j.physb.2005.11.032 (Original work published 2006)