Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Horeglad, P.;Nocton, G.;Filinchuk, Yaroslav;Pécaut, J.;Mazzanti, M.
(2009) Chemical Communications — n° 14, p. 1843-1845 (2009)

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Authors
  • Horeglad, P.
    Author
  • Nocton, G.
    Author
  • Author
  • Pécaut, J.
    Author
  • Mazzanti, M.
    Author
Abstract
A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO2Py5][KI2Py2]} n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates. © 2009 The Royal Society of Chemistry.
Affiliations
  • ESRF, Grenoble (France)Chimie

Citations

Horeglad, P., Nocton, G., Filinchuk, Y., Pécaut, J., & Mazzanti, M. (2009). Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand. Chemical Communications, 14, 1843-1845. https://doi.org/10.1039/b821398d (Original work published 2009)