Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions
(2007) Polyhedron — Vol. 26, n° 9-11, p. 2259-2263 (2007)
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- New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.
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Dirtu, M. M., Garcia, Y., Nica, M., Rotarii, A., Linares, J., & Varret, F. (2007). Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions. Polyhedron, 26(9-11), 2259-2263. https://doi.org/10.1016/j.poly.2006.11.009 (Original work published 2007)