(η2-allylammonium)aquabis(sulfamato-N)copper(I)

Melnyk, O.P.;Schollmeyer, D.;Olijnyk, V.V.;Filinchuk, Yaroslav
(2001) Acta crystallographica. Section C , Crystal structure communications — Vol. 57, n° 2, p. 151-153 (2001)

Files

No attached file found for this publication.

Details

Authors
Abstract
The CuI atom in the title complex, [Cu(NH2SO3)2- (C3H8N)(H2O)], is coordinated by the C double bond C bond of the allylammonium cation, two N atoms of the sulfamate anions and the O atom of the H2O molecule in the apical position. Thus, the central atom is in a distorted trigonal-pyramidal environment. Strong N-H...O and O-H...O contacts connect separate moieties of the complex into a three-dimensional framework. The title compound is representative of hitherto unknown copper(I)-sulfamate π-complexes.
Affiliations

Citations

  • APA
  • Chicago
  • FWB

Melnyk, O. P., Schollmeyer, D., Olijnyk, V. V., & Filinchuk, Y. (2001). (η2-allylammonium)aquabis(sulfamato-N)copper(I). Acta crystallographica. Section C , Crystal structure communications, 57(2), 151-153. https://doi.org/10.1107/S0108270100016218 (Original work published 2001)