An in situ generated samarium complex as a practical catalyst for the efficient intramolecular hydroamination of non-activated alkenes

Quinet, Coralie;Ates, Ali;Marko, Istvan
(2008) Tetrahedron Letters — Vol. 49, n° 34, p. 5032-5035 (2008)

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  • Quinet, CoralieUCLouvain
    Author
  • Ates, AliUCLouvain
    Author
  • Marko, IstvanUCLouvain
    Author
Abstract
Mixing Sml(2) and NaN(TMS)(2) generates in situ an efficient catalyst that promotes the intramolecular hychoamination of non-activated olefins. A wide range of aminoolefins can be cyclised smoothly using this simple protocol. Mechanistic studies led to the identification of the putative active catalyst. (c) 2008 Elsevier Ltd. All rights reserved.
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Quinet, C., Ates, A., & Marko, I. (2008). An in situ generated samarium complex as a practical catalyst for the efficient intramolecular hydroamination of non-activated alkenes. Tetrahedron Letters, 49(34), 5032-5035. https://doi.org/10.1016/j.tetlet.2008.06.053 (Original work published 2008)