Copper-catalyzed vinylsilane allylation

Cornelissen, Loïc;Vercruysse, Sébastien;Sanhadji, A.;Riant, Olivier
(2014) European Journal of Organic Chemistry — Vol. 2014, n° 1, p. 35-38 (2014)

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Authors
  • Cornelissen, LoïcUCLouvain
    Author
  • Vercruysse, SébastienUCLouvain
    Author
  • Sanhadji, A.UCLouvain
    Author
  • Riant, OlivierUCLouvain
    Author
Abstract
Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper(I) salt, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. Hereby is described a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using copper(I) salts, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. TBAT = tetrabutylammonium difluorotriphenylsilicate. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Cornelissen, L., Vercruysse, S., Sanhadji, A., & Riant, O. (2014). Copper-catalyzed vinylsilane allylation. European Journal of Organic Chemistry, 2014(1), 35-38. https://doi.org/10.1002/ejoc.201301360 (Original work published 2014)