Spin transition in [Fe(phen)(2)(NCS)(2)] - mu SR study

Garcia, Yann;Ksenofontov, V;Campbell, SJ;Lord, JS;Gutlich, P;et.al.
(2004) Physica Status Solidi. A: Applied Research — Vol. 201, n° 15, p. 3309-3313 (2004)

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  • Garcia, Yannorcid-logoUCLouvain
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  • Ksenofontov, V
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  • Campbell, SJ
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  • Lord, JS
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  • Boland, YvesUCLouvain
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  • Gutlich, P
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Abstract
The reversible thermal spin transition which occurs in [Fe(phen)(2)(NCS)(2)] around T-1/2 similar to 177 K has been investigated by muon spin relaxation (muSR) (similar to10-280 K). The depolarisation curves are well described by two Lorentzian lines represent fast and slow components in the decay curves, with the initial asymmetry parameter of the fast component found to track the spin transition in [Fe(phen)2(NCS),]. Comparison of zero-field and transverse field (20 Oe) muSR measurements shows that diamagnetic muonic species occur over the entire temperature range.
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Garcia, Y., Ksenofontov, V., Campbell, S., Lord, J., Boland, Y., & Gutlich, P. (2004). Spin transition in [Fe(phen)(2)(NCS)(2)] - mu SR study. Physica Status Solidi. A: Applied Research, 201(15), 3309-3313. https://doi.org/10.1002/pssa.200405458 (Original work published 2004)