A metal-organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

Boland, Yves;Tinant, Bernard;Safin, Damir;Marchand-Brynaert, Jacqueline;Garcia, Yann;et.al.
(2012) CrystEngComm — Vol. 14, n° 23, p. 8153-8155 (2012)

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Authors
  • Boland, YvesUCLouvain
    Author
  • Tinant, BernardUCLouvain
    Author
  • Safin, DamirUCLouvain
    Author
  • Marchand-Brynaert, JacquelineUCLouvain
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  • Garcia, Yannorcid-logoUCLouvain
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Abstract
Reaction of the asymmetric ligand, 1-[3′-(1,2,4-triazol-4-yl)propyl] tetrazole (L) with Cu(BF 4) 2 in water leads to the Cu II metal-organic framework [CuL(OH)]BF 4 (I). According to X-ray analysis, L connects four Cu II ions, where the 1,2,4-triazole and tetrazole units exhibit a bridging bis-monodentate μ 2-N1,N2 and a unique μ 2-N2,N3 coordination modes, respectively. © 2012 The Royal Society of Chemistry.
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Boland, Y., Tinant, B., Safin, D., Marchand-Brynaert, J., Clérac, R., & Garcia, Y. (2012). A metal-organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand. CrystEngComm, 14(23), 8153-8155. https://doi.org/10.1039/c2ce26257f (Original work published 2012)