Simultaneous generation of anionic and neutral palladium(II) complexes from eta(3)-allylpalladium chloride dimer and fluorinated beta-enaminones
(2003) European Journal of Organic Chemistry — n° 24, p. 4717-4720 (2003)
Files
No attached file found for this publication.
Details
- Authors
- Abstract
- Reactions between eta(3)-allylpalladium chloride dimer, 1,8-di-azabicyclo[5.4.0]undec-7-ene (DBU) and 1-amino-2-fluoro-1-perfluoroethyl-3 -phenylprop-1-en-3-one or 1,12-diamino-2,11-difluoro-1,12-bis(perfluorobutyl)dodeca-1,11-diene- 3,10-dione simultaneously provided two types of Pd-II complexes. One is an anionic eta(3)-allylpalladium complex with protonated DBU as counterion while the other is a neutral eta(3)-allyl(beta-ketoiminato)palladium complex. A mechanism involving the amidine function of DBU in the formation of the two complexes is proposed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
- Affiliations
Citations
Bouquillon, S., Bouillon, JP., Thomas, L., Plantier-Royon, R., Chanteau, F., Tinant, B., Henin, F., Portella, C., & Muzart, J. (2003). Simultaneous generation of anionic and neutral palladium(II) complexes from eta(3)-allylpalladium chloride dimer and fluorinated beta-enaminones. European Journal of Organic Chemistry, 24, 4717-4720. https://doi.org/10.1002/ejoc.200300557 (Original work published 2003)