Copper(I) nitrate π-complexes: Synthesis and structure of [Cu(CH2=CH-CH2-CN)(NO3)]
(1997) Russian Journal of Coordination Chemistry — Vol. 23, n° 11, p. 791-793 (1997)
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- Authors
- Abstract
- Crystals of the CuNO3 π-complex with allyl cyanide are obtained by ac electrochemical synthesis, and their structure is determined [DARCh diffractometer, MoKα radiation, R = 0.022 for 902 independent reflections, F ≥ 4σ(F)]. The π-complex crystallizes in space group P21/b, a = 10.137(2), b = 9.671(2), c = 6.848(1) Å, α = 101.75(2)°, Z = 4. The copper coordination polyhedron is a distorted tetrahedron formed by two O atoms, and N atom of the cyano group, and a C=C bond. The structure of the compound is compared with those of previously studied CuNO3 π-complexes. © 1997 MAEe Cyrillic signK Hayκa/Interperiodica Publishing.
- Affiliations
Franko LVIV University (Ukraine) Chimie
Citations
Filinchuk, Y., Oliinik, V. V., & Davydov, V. N. (1997). Copper(I) nitrate π-complexes: Synthesis and structure of [Cu(CH2=CH-CH2-CN)(NO3)]. Russian Journal of Coordination Chemistry, 23(11), 791-793. https://hdl.handle.net/2078.5/163953 (Original work published 1997)