Analysis of vibration-rotation bands of OCS in the 5.3 mu m region using a tunable Q-switched spin-flip Raman laser
(1977) Molecular Physics : an international journal at the interface between chemistry and physics — Vol. 33, n° 3, p. 603-610 (1977)
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- Abstract
- With the use of a conventional high-resolution grating spectrometer and a Q-switched spin-flip Raman laser (SFRL), carbonyl sulphide ro-vibrational bands between 1852 and 1914 cm/sup -1/ have been measured and analysed. Rotational constants for seven bands have been calculated, including bands of the two isotopic species O/sup 13 /CS and OC/sup 34/S occurring in natural abundance. The 12/sup 0/0 larr 00/sup 0/0 band of OCS has been measured with an absolute accuracy of 0.002 cm/sup -1/ and so can be used for the calibration of the SFRL spectra in the 5.3 mu m region.
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Citations
Fayt, A., Van Lerberghe, D., Kupfer, J. P., Pascher, H., & Hafele, H. G. (1977). Analysis of vibration-rotation bands of OCS in the 5.3 mu m region using a tunable Q-switched spin-flip Raman laser. Molecular Physics : an international journal at the interface between chemistry and physics, 33(3), 603-610. https://hdl.handle.net/2078.5/44916 (Original work published 1977)